...provides an introduction to the principles and general properties of organometallic compounds...supplies practical information about reaction mechanisms... (SciTech Book News, Vol. 25, No. 2, June 2001) "Each edition of this organometallics book...keeps getting better...useful as a reference...useful for undergraduate and graduate students." (Choice, Vol. 38, No. 11, July 2001)
General Properties of Organometallic Complexes; Metal Alkyls, Aryls, and Hydrides and Related sigma-Bonded Ligands; Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions; Complexes of PI-Bound Ligands; Oxidative Addition and Reductive Elimination; Insertion and Elimination; Nucleophilic and Electrophilic Addition and Abstraction; Homogeneous Catalysis; Physical Methods in Organometallic Chemistry; Carbenes, Metathesis, and Polymerization; Applications of Organometallic Chemistry; Clusters and the Metal-Metal Bond; Applications to Organic Synthesis; Oxidation and High-Oxidation-State Complexes; Bioorganometallic Chemistry; Useful Texts on Allied Topics; Major Reaction Types; Solutions to Problems; Index.
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ROBERT H. CRABTREE, PhD, is a professor in the Department of Chemistry at Yale University.