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Chiral Sulphur Reagents: Applications in Asymmetric and Stereoselective Synthesis

Series: New Directions in Organic and Biological Chemistry

By: Marian Mikolajczyk, Josef Drabowicz and Piotr Kielbasinski

CRC Press

Hardback | Dec 1997 | #88895 | ISBN: 0849391202
Availability: Usually dispatched within 6 days Details
NHBS Price: £111.00 $136/€125 approx

About this book

Over the last three decades, more than 40 different classes of chiral (mirror-image) sulfur compounds have been described, and a number of useful procedures and applications have been developed for their use. Emphasizing modern methodologies, Chiral Sulfur Reagents demonstrates the great potential of enantionmerically pure sulfur reagents in transimitting chirality to other centers. Each chapter highlights the synthesis and synthetic uses of a particular class of chiral sulfur reagent, followed by examples of the most important experimental procedures.


Structure-Chirality Relationship in Organic Sulfur CompoundsChiral Sulfinic Acid DerivativesSulfinic EstersChiral Sulfinamides and N-AlkylidenesulfinamidesChiral Sulfoxidesa-Sulfinyl Carbanions (THAT "a" IS A GREEK "a" SO "alpha" -- USE SYMBOL FONT)Dialkyl and Alkyl Aryl SulfoxidesAllyl SulfoxidesAlkyl and Arylsulfenylmethyl Sulfoxidesa-Sulfinyl-, a-Sulfonyl, and a-Sulfoximino Sulfoxides (ALL 3 OF THOSE ARE GREEK "a" SO USE SYMBOL FONT)a-Halogeno Sulfoxides (THAT "a" IS A GREEK "a" SO "alpha" -- USE SYMBOL FONT)a-Phosphoryl Sulfoxides and a-Sulfinyl Phosphonium Salts (THOSE "a"s are GREEK "a" SO "alpha" -- USE SYMBOL FONT)b-Oxosulfoxides (THAT "b" IS A GREEK "b" SO "beta" -- USE SYMBOL FONT) and Related DerivativesAcyclic a,b-Unsaturated Sulfoxides (THAT "a" IS A GREEK "a" and the "b" is a Greek "b" -- USE SYMBOL FONT)Cycloalkenone SulfoxidesChiral Sulfilimines and SulfoximinesSynthesis of Chiral SulfiliminesSynthesis of Chiral SulfoximinesChiral Sulfilimines and Sulfoximines in Asymmetric SynthesisExamples of Experimental ProceduresChiral "Onium" Derivatives of Sulfur and Chiral Sulfur YlidesPreparation of Chiral Sulfur Onium Salts and YlidesSynthetic Application of Chiral Sulfur "Onium" Salts and YlidesExamples of Experimental ProceduresReferencesIndex

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