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Application of Transition Metal Catalysts in Organic Synthesis

By: L Brandsma, SF Vasilevsky and JD Verkruijsse

350 pages, Illus

Springer-Verlag

Hardback | Dec 1997 | #88901 | ISBN: 3540628312
Availability: Usually dispatched within 1-2 weeks Details
NHBS Price: £118.50 $153/€141 approx

About this book

Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. This book selects and checks the experimental procedures illustrating the catalytic use of copper, nickle and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields at high turn-over rates.


Contents

Catalysts, Ligands and Reagents; Procedures for the Preparation of Halogen Compounds; Cross Coupling between 1-Alkynes and 1-Bromoalkynes; Copper Catalyzed Aminoalkylation of Acetylenes; Copper(I)halide Catalyzed Oxidative Coupling of Acetylenes; Copper(I)halide Catalyzed Substitution of sp2-Halogen by Alkoxide; Copper Catalyzed Carbon-Carbon Bond Formation by 1,1- and 1,3-Substitution Reactions; Nickel Catalyzed Iodo-Dechlorination and Iodo-Debromination of sp2-Halides; Nickel and Palladium Catalyzed Cyanation of sp2-Halides and sp2-Triflates; Couplings of Acetylenes with sp2-Halides; Nickel and Palladium Catalyzed Cross Coupling Reactions with Organometallic Intermediates.

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